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Chapters 3 and 4 - Coggle Diagram
Chapters 3 and 4
Chapter 3: Water and Life
Emergent Properties
Four emergent Properties
Temperature Moderation
Kinetic Energy = energy of movement
Thermal energy = kinetic energy of random movement of atoms/molecules
Temp = average kinetic energy of molecules
Thermal energy = total kinetic energy
Heat = thermal energy going from one thing to another
calorie = heat needed to change 1g of substance by 1C
kilocalorie = 1,000cal
Specific heat = heat needed for 1g substance to change temp by 1C
Expansion
Water less dense as solid (ice floats)
H bonds keep molecules further apart when frozen (water expands)
Water has greatest density at 4 degrees Celsius
Allows marine life to survive cold periods
Cohesion
Cohesion = substance "sticks" to itself
Hydrogen bonds hold water together
Surface Tension
How difficult it is to break/stretch surface of substance
Transport of Water Against Gravity
Contributors
Cohesion
Adhesion (different molecules sticking together)
Adhesion and Cohesion create upward pull
Versatility as Solvent
Solution = homogenous mix of substances
Solvent = dissolving agent
Solute = gets dissolved
Aqueous solution = water is the solvent
Water's polarity makes it a diverse solvent
Hydration shell = sphere of water molecules around dissolved ion
Compatibility
Hydrophobic
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Hydrophilic
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Solute Concentration
Molecular mass = sum of all masses of atoms in a molecule
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Evolution
Presence of water on Mars suggests possibility of life
Acidic and Basic Conditions
H+ = a hydrogen ion
Water can transfer a H+ to another
Creates OH- (hydroxide ion) and H3O+ (hydronium ion)
pH scale
pH = -log[H+] (aka measure of hydrogen ion concentration)
pH of 7 = neutral (water's pH = 7)
Lower pH = more acidic
Higher pH = more basic
pH increases/decreases tenfold
Buffers
Minimize pH changes in solutions
Donates and accepts hydrogen ions when needed
Example: carbonic acid
Acids and Bases
Acid
Increases hydrogen ion concentration
Higher H+ = acidic
Strong acid = dissociates completely
Base
Lowers hydrogen ion concentration
accepts hydrogen ions directly
dissociates to form hydroxide ions that combine w/ hydrogen ions
Higher OH- = basic solution
Strong base = dissociates completely
Acidification
Fossil fuels release carbon dioxide
~25% absorbed by oceans
dissolves to make carbonic acid
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Bonding
Hydrogen bonds
Form between water molecules
Partially charged H is attracted to partially charged O
Gives water its many properties
Polar Covalent Bonds
Form between O and H within molecule
O more electronegative than H
Electrons closer to O
O becomes partially negative
Each O can form 2 hydrogen bonds
H becomes partially positive
Each H can form one hydrogen bond
Chapter 4: Carbon and the Molecular Diversity of Life
Carbon's Diversity
Bonds
Valence = electrons needed to fill valence shell
C has valence of 4
C usually single or double bonds in organic molecules
Molecule's shape central to its function
C with four bonds has tetrahedral shape
Carbon's most common bonding partners
H, O, and N
Molecular Diversity
C skeletons = base for most organic molecules
Types of organic molecules
Isomers
Have same chemical formula, different structure + properties
Structural isomers
Different covalent arrangements
Cis-trans isomers
cis = Xs on same side
trans = Xs on opposite sides
Enantiomers
due to asymmetric carbon
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Hydrocarbons
Have only C and H
Examples
Fats (the hydrocarbon tails)
Major component in petroleum
Characteristics
Can have double bonds
Shape + size vary
Key Chemical Groups
Chemical Groups
Functional groups = directly involved in chemical reactions
7 most important groups in biological processes
carbonyl
reactive
hydrophilic
hydroxyl
reactive
hydrophilic
carboxyl
reactive
hydrophilic
amino
reactive
hydrophilic
sulfhydryl
reactive
hydrophobic
phosphate
reactive
hydrophilic
methyl
not reactive; serves as "tag"
ATP
ATP = adenosine triphosphate
Components
Adenosine + 3 phosphate groups
Function
Source of energy
Releases energy by losing a phosphate
Phosphate lost = an inorganic phosphate
ATP becomes ADP (adenosine diphosphate)
Reaction occurs when ATP reacts with water
Reaction is reversible
Organic Chemistry
Major elements of Life
C, H, O, N, S, P = major elements of life
Stanley Miller Experiment
First synthetization of organic compounds in a lab
Proved abiotic synthetization was possible
Possible early stage of life's origin