Energy from fuels

Combustion

Fossil Fuels

Combustion reactions

Types of Combustion

Formation of fossil fuels

Types of fossil fuels

combustion is a process of chemical change or transformation that involves an element or compound burning in oxygen.

It is a redox reaction as it involves a transfer of electrons from the metal or non-metal (reducing agent) to oxygen (oxidising agent)

incomplete combustion

complete combustion

hydrocarbon and alcohols are used as fuel as their combustion reaction releases energy at a reasonable rate to be useful. however, the reaction is not spontaneous as though they are energetically less stable as compared to their combustion products, they are kinetically stable, and hence have a sufficiently high activation energy for them to be stored and transported safely

Metals form basic, ionic oxides while non-metals form acidic, covalent oxides

complete combustion takes place when the supply of air is not limited, and it forms carbon dioxide and water as products

the complete combustion of hydrocarbon involves the breaking of carbon chains which results in the production of CO2 and H2O

when the air supply is limited or when the compound has a high percentage carbon by mass, and it produces carbon monoxide and carbon (soot)

especially so in hydrocarbons

The amount of soot produced can be used to distinguish different hydrocarbons

incomplete combustion produces less heat as compared to complete combustion ==> the formation of carbon dioxide is more exothermic than the formation of carbon monoxide and carbon

Ideal fuel

coal, crude oil and natural gases are examples of fossil fuels

readily available, plentiful, cheap, provide high quality energy at a reasonable rate, have minimal impact on the environment

Most of the energy used by humans is harnessed indirectly from the sun by burning fossil fuels

Renewable and Non-renewable sources

non renewable / non-sustainable resources: Fossil fuel

  • Used at a rate that is faster than it can be replenished

Renewable resources: Wood (ancient technology)

  • Trees that are chopped down to provide fuel can be replanted
  • takes millions of years to form

energy from fossil fuels comes from the sunlight which is trapped by green plants millions of years ago. And they are produced by the slow and partial decomposition of plant and animal matter, that are trapped in the absence of air. O2 is lost at a faster rate as compared to other elements, from biological molecules and hence the reduced biological molecules are mainly hydrocarbons

Coal

Advantages

Disadvantages

Formation

Uses

The most abundant fossil fuel

it is a combustible sedimentary rock formed from the remains of plant life that is subjected to geological heat and pressure, which changed the plant material in stages to increase percentage of carbon content

Contains 80 - 90% carbon content by mass ; it occurs in many areas around the world but mainly in the northern atmosphere

Crude oil

Advantages

Disadvantages

Formation

complex mixture of straight chained, branched chain saturated alkanes, cycloalkanes, aromatics compounds, as well as in small amounts, compounds of nitrogen, oxygen and sulfur.

Uses

it is formed over millions of years from the remains of marine organisms (plants and animals) that are trapped under layers of rocks. under conditions of high temperature, high pressure, presence of bacteria and absence of air, the organic matter will decay

limited supply and hence other options have to be considered

important chemical feedback for the production of important organic compounds, such as polymers, pharmaceuticals, dyes and solvents

supplies fuels used for transportation and electricity generation

Coal

Advantages

Disadvantages

Formation

formed millions of years ago by the action of heat, pressure and maybe bacteria on buried organic matter. the gas is trapped in geological formations, capped under impermeable rocks.

Uses

main constituent is methane and some compounds of nitrogen and sulfur as impurities

formed by the decomposition of coal and crude oil deposits (occur naturally on its own as a layer above oil reservoir or dissolved under pressure in oil)

cleanest of all 3 fossil fuels (lower percentage carbon content)

impurities are easily removed

easily transported in pipelines so little energy is required to transport it from the ground to consumers

massive capital is needed to set up a distribution network