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Zn metal in AZIBs, mild acidic electrolyte (pH 4~6), TCPP, Zn…
Zn metal in AZIBs
mild acidic electrolyte (pH 4~6)
TCPP
Zn reversibility (stripping/plating)
Zn dendritic growth
HER
corrosion
hydrophilicity
zincophilicity
sp2-hybridized carbon-rich
electron-donating nitrogen
COO- functional group
hydrogen bonding with ZSH
byproduct (ZSH formation) - dead Zn
uniform SEI formation
suppressing HER
uniform ion flux
fast Zn supply
protecting from corrosion
no dendritic growth
no clustering nucleation
low nucleation overpotential
low growth overpotential
long cycle life
more reliable over long cycle
LSV
Contact angle
SEM
FT-IR
SEM
electrochemical data
FIB-SEM
TOF-SIMS depth
XPS depth
CA
SO4- immobilization
EIS
comparison to ZnTCPP