Thermal Physics

Internal energy

Boiling and condensation

Evaporation

Melting and solidification

-Unit in joule
-The particles in a substance are in continuous motion and attractive forces exist between these such as intermolecular bonds

Internal potential energy
-Due to stretching of bonds as particles move
-Potential energy between the particles depends on forces between them and how far apart they are

Internal kinetic energy
-Due to motion of particles
-Directly related to temperature- the higher the temperature, the more vigorous the motion of particles

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Melting
-Temperature does not change during melting
-Definite temperature for pure substances
-Energy is absorbed to break down forces of attraction between particles and only internal KE is changed.

Solidification
-Temperature does not change during freezing
-Definite temperature for pure substances
-Energy is released to form strong forces of attraction and only internal KE is changed.

Boiling
-No change in temperature
-Definite temp for pure substances
-Energy is absorbed to break down forces of attraction between particles and only internal KE is changed.

Condensation
-No change in temp
-Definite temp for pure substances
-Energy is released to form strong forces of attraction and only internal KE is changed.

Similar to boiling but has differences

It causes cooling

Evaporation:
-Occurs at any temperature
-Relatively slow
-Takes place only at the surface of the liquid
-No bubbles are formed
-Temp may change
-External thermal energy not needed

Boiling:
-Occurs at a particular temp
-Relatively fast -Takes place throughout the liquid
-Bubbles are formed
-Temp remains constant
-External thermal energy needed

eg. perfume, swimming and coming out afterwards and fridge

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Transfer of thermal energy

Model of matter

Solid

Liquid

Gas

Randomly arranged and far apart

Move rapidly in all directions

Arranged in an orderly manner

Vibrate about fixed positions

Randomly arranged and further apart

Slide past one another

Conduction

Convection

Radiation

Real-life examples

Transfer of thermal energy without any flow of medium

Travel from high temp to low

Only in solids and is faster in metals due to free electron diffusion

Not efficient in liquids and gases

Transfer of thermal energy by convection in a fluid due to difference in density using convection currents

Only in liquids and gases

Transfer of thermal energy without a medium through EM waves

Affected by colour ( darker is better emitter), texture (rougher is better), surface temperature (higher is better), surface area (larger is better)

Conduction

Convection

Radiation

Good- cooking utensils, soldering iron tips

Bad/Poor- handles of appliances, table mats, clothing, windows

Electric kettles, hot water systems, air-con

Green houses, vacuum flasks