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ORGANIC REACTION, ADDITION REACTION, ELIMINATION REACTION, Substitutions…
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ADDITION REACTION
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MARKOUNIKOVS RULE
The addition of unsymmetrical reagents such as HX HO, HOX etc. to unsymmetrical alkene occurs in such a way that the negative part of the addendum goes to that carbon atom of the double bond which carries lesser member of hydrogen atom
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ELIMINATION REACTION
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SAYTZEFF'S RULE
The favored product in dehydrohalogenation reactions is the alkene with the greatest amount of alkyl groups connected to the doubly bound carbon atoms.”
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Substitutions are initiated by free radical. The reaction takes place by a free radical chain mechanism.
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involves the loss of halogen and the hydrogen atom from a carbon adjacent to the one losing the halogen (beta-elimination).
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This reaction involve the replacement of an atom or a group of atoms present in the organic compound by the nucleophile.
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a group or radical attached to a carbon atom is replaced by another atom or group of atoms called substituents.
This are initiated by the electrophilic reagents and involves the replacement of atom or a group of atoms present in the organic compound by the electrophile.
