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CHM2012 - Coggle Diagram

- - - - Pinacol
        
        A methyl group migrates to form a more stable carbocation, which deprotonates to yield a stable product
      - Beckmann
        
        An oxime converts into an amide by intermolecular rearrangement
      - Baeyer-Villiger Oxidation
        
        Ketones are converted into esters by peroxy acids
      - Tiffenau-Demjanov
    - - Less likely to rearrange sue to high-energy nature of their transition states
        
        Favorskii
  - - - Primary amines react with carbonyl compounds to from imines through an addition-dehydration mechanism
    - - Secondary amines react with carbonyls to form enamines, as imine formation is not possible due to the lack of hydrogen atom on the nitrogen
        
        Enamines are formed through an E1 mechanism, where the immonium loses a proton to form the C=C bond
- - - - Bond connected Cd-R attacks the Carbon on the acyl chloride
- - - - TMS, Tetramethylsilane, (CH3)4Si
        
        Used because it has a low boiling point and non-polar, meaning it can be easily removed
        
        Used because it is chemically inert, so does not react with other samples