Chem Paper 1 - Final Exams

C1

L1 - Periodic Table

Newlands: Conceived the law of octaves, arranged in increasing atomic weight, some elements were grouped incorrectly and the table was incomplete.

Mendeleev: Increasing atomic weight, switched the order of some elements, left gaps for undiscovered elements. He predicted the properties of these elements and was proven right.

Modern: Increasing proton number, noble gasses included. (Mendeleev had to correct order due to presence of isotopes).

Bottom = Proton number, Top = Mass number

L2 - Group 1

Soft: can be cut with a knife.

Oxygen:
All react rapidly and from a metal oxide layer when exposed.

Chlorine:
React rapidly with chlorine.

Water:

  • Lithium: Fizzes rapidly (gas), turns water alkali.
  • Sodium: Fizzes more rapidly, melts, forms a ball and moves across the surface.
  • Potassium: Fizzes more rapidly, releases hydrogen that burns with a lilac flame.
    [Hydroxides formed]

Reactivity increases as you go down to group due to a increased shielding effect. Also, the attraction between the outermost electron and positively charged nucleus decreases.

MP decreases as you go down.

L3 - Group 7

Halogens are diatomic, forming a covalent molecule.

The melting point of halogens increases as you go down the group.

Reactivity decreases as you move down the group.

L4 - Noble Gasses

Boiling points increase as you move down the group.

Dissolve in water to form acidic solutions.

C2

L1 - Ionic Bonds

Form between metal and non-metal ions transferring electrons. These bonds are held together through electrostatic attraction.

Ionic compounds are structured in giant ionic lattices; in these lattices, all ions possess a strong electrostatic attraction to oppositely charged ions. These ionic lattices have a very high melting and boiling point. These compounds do not conduct electricity unless they are molten or aqueous as charges are free to move here.

L2 - Covalent Bonds

Covalent bonds are formed when two non-metals share electrons. These bonds are strong but the intermolecular forces between simple covalent molecules are weak and can be easily overcome.

Polymers are very long chains of covalent molecules, as the length of these chains increases, boiling point increases also.

L3 - Giant Covalent Structures

Giant covalent structures form from repeating covalent lattices, they do not generally conduct electricity (graphite does however).

In graphite, each carbon atom bonds with three other carbon atoms in a hexagonal repeating pattern, meaning that for every carbon atom, there is a free delocalised electron that is free to carry charge. Graphite can slide due to weak IMF between layers.

L4 - Fullerenes

Graphene is a single layer of graphite, meaning that it is not soft but is still a good thermal and electrical conductor.

A fullerene is an allotrope of carbon.

Carbon nanotubes are a cylindrical form of graphene, they can conduct electricity and heat well, have a high tensile strength and have a high surface area to volume ratio. These nanotubes can be used in the production of electronics but also in the reinforcement of tennis rackets.

Buckminsterfullerene is an altered form of graphene with a near-spherical shape. They have a very high surface area to volume ratio. They have the ability to deliver drugs in the body due to their hollow shape. They can also be used as catalysts and in lubricants due to their ability to roll.

L5 - Metallic Bonding

L6 - Nanoparticles

Disadvantages of nanoparticles include their novelty (they have not been fully researched so their effects on our body have not been fully researched).

Metallic bonds form between two metals.They are held together by the electrostatic attraction between positive metal ions and a sea of delocalised electrons.

Alloys contain two or more different metals, this disrupts the uniform structure of the metal and prevents layers from sliding, making alloys harder, more durable and more resistant to corrosion.

Nano particles typically have a diameter from 10nm to 100nm. They have a large surface area to volume ratio.

Nanoparticles can be used at catalysts, in electronics and medicines. Silver nanoparticles have antibacterial properties.

C3

L1 - Moles and Relative Mass

There are 6.022 x 10^23 atoms within a mole, no matter the element.

Relative atomic mass = ((Abundance of A x Mass of A) + (Abundance of B x Mass of B)) / 100

Mass = Relative Formula Mass x Number of Moles

L2 - Limiting Reactants

The limiting reactant is the reactant that gets used up first in the reaction, it limits the reaction. Using reactants in excess ensure that all of the limiting reactant will have been used up.

L3 - Percentage Yield

A higher percentage yield in industry ensures that minimal waste is produced, production is optimally efficient and maximum profit is made. It could also reduce consumer cost.

Percentage Yield = (Actual / Theoretical) x 100

Factors that result in a yield < 100:

  • Reaction may be reversible (didn't go to completion).
  • Some of the reactants may have been left in the aparatus.
  • Undesired side-reactions may have taken place.
  • Reactants may not be pure.

L4 - Atom Economy

Reactions with higher atom economies render a reaction more efficient and aids in sustainable development. It means that less waste is produced in the reaction.

AA = (Relative formula mass of desired product / Relative formula mass of all reactants) x 100

REVISE CALC

L5 - Titrations and Concentrations

Concentration = Moles / Volume

Concentration is the amount of solute that has dissolved in a certain amount of solvent.

Method (adding alkali to acid):

  • Equipment cleaned with distilled water and the solution you are using to stabilize the pH and prevent contamination.
  • Measure out 25cm^3 of acid (of a known concentration) using a volumetric pipette; this should be drawn up using a pipette filler, reading it from the bottom of the meniscus.
  • Add the acid to a conical flask and then add a few drops of phenolphthalein indicator.
  • Measure out a volume of alkali using a burette (recording the initial volume).
  • Place the conical flask on a white tile with the burette tap above the flask.
  • Slowly add the alkali to the acid in the flask, adding dropwise when the endpoint is nearly reached.
  • When the solution just changes from colourless to slight pink. Record the volume of alkali used.
  • These steps should be repeated until concordant results are obtained (within 0.1cm^3 of each other).

L6 - Volume of Gasses

1 litre = 1dm^3

1 mol of any gas at room temperature and pressure occupies 24dm^3 of space.

REVISE CALC

C4

L1 - Oxidation and Reduction

More unreactive metals will exist in a pure form within the Earth. More reactive metals will be found in their metal ore forms. Metals that are less reactive than carbon can be extracted from their ores through the use of carbon reduction.

The higher a metal is on the reactivity series, the more reactive it is and the more elements it can replace from their compounds.

A more reactive metal will have a greater tendency to form positive ions.

L2 - Metals and Acids

K, Na and Li will react violently with acid. Tin and lead react slowly with warm acid and copper, gold, etc do not react with acid.

If the pH of a solution decreases by one order of magnitude, the concentration of hydrogen ions within increases by a factor of 10.

Metal + Acid --> Salt + Hydrogen

L3 - Neutralisation and Carbonates

Acids can be neutralised with alkalis (soluble metal hydroxides) or bases (insoluble metal hydroxides).

Forming Crystals Method:

  • Pour given dilute acid into a beaker and heat it slightly with a bunsen burner.
  • Add metal oxide or carbonate in excess and stir until gas is no longer given off (all the acid has reacted).
  • Filter off excess metal oxide or carbonate using filter paper and a funnel.
  • Pour the solution into an evaporating basin.
  • Use an electric heater to slowly evaporate off the water from the solution.

Acids produce hydrogen ions in aqueous solutions. Strong acids fully ionise in aqueous solutions (these include hydrochloric acid, nitric acid and sulphuric acid). Weak acids only partially ionise in an aqueous solution, these reactions are often reversible and weak acid examples include carbonic acid, ethanoic acid and citric acid.

L4 - Electrolysis

During the electrolysis of an aqueous solution, hydrogen is produced at the cathode is the metal is more reactive than hydrogen. At the anode, oxygen gas will be produced unless there is a halide ion present within the compound.

For the electrolysis of molten aluminium oxide, it is first mixed with cyolite to reduce its melting point, meaning that less energy has to be expended: this is more economically viable.

C5

L1 - Endo and Exo

Within exothermic reactions, energy is transferred from the system to the surroundings.

Exo: Enthalpy change < 0

Exo: Combustion, oxidation, neutralisation, respiration, combustion.

Endo: Enthalpy change > 0

Endo: Thermal decomposition, photosynthesis.

L2 - Required Prac

Method:

  • Place a polystyrene cup inside a glass beaker to make it more stable (prevent spilling).
  • Measure an appropriate volume of liquid (25cm^3).
  • Place the solution in the polystyrene cup and record the temperature.
  • Add the second solution/substance, place a lid on the cup and measure the maximum or minimum temperature reached.
  • Change the independent variable.

L3 - Reaction Profiles

Activation energy is the minimum amount of energy needed for a reaction to occur. It is the minimum amount of energy that particles must have in order to react.

L4 - Cells and Batteries

Within chemical cells, electrodes with greater differences in reactivity will produce a greater voltage. Cells contain chemicals which react to produce electricity.

In non-rechargeable batteries, the chemical reactions stop when one of the reactants is used up. Alkaline batteries are non-rechargeable. Rechargeable cells and batteries can be recharged with the application of an external current that reverses the chemical reaction.

L5 - Fuel Cells

Fuel cells product a voltage continuously. Hydrogen fuel cells use oxygen and hydrogen to produce water and a voltage. Hydrogen fuel cells are quieter, need less maintenance and only produce water but hydrogen is explosive / needs to be stored, is not supported as much infrastructurally and are expensive.

2H{2} + O{2} --> 2H{2}O

Cathode: 2H{2}(g) --> 4H+ + 4e[-]
Anode: O{2}(g) + 4H+ + 4e[-] --> 2H{2}O(g)

Hydrogen fuel cells oxidise their fuel electrochemically.