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MIND MAP 3, SHARIFAH AZRA BT ABDUL KADIR - Coggle Diagram
MIND MAP 3
Lattice Vibration I
Crystals Dynamic
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Atomic motions are governed by the forces exerted on atoms
when they are displaced from their equilibrium positions
To calculate the forces it is necessary to determine the wavefunctions and energies of the electron within the crystals
In crystal dynamics we will use the harmonic approximation, amplitude of the lattice vib is small . At >amplitude some unharmonic effects occur.
Hooke's Law
One of the properties of elasticity is that it takes about twice as much force to stretch a spring twice as far
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Elastic Region ends is called the inelastic
limit, or the proportional limit
The inelastic Limit is the point at which permanent deformation
occurs and The Proportional Limit is the point at which the deformation is no longer directly proportional to the applied force
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Heat Capacity
The energy given to lattice vibrations is the dominant contribution to the heat capacity in most solids. In non-magneticinsulators, it is the only contribution.
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Lattice Vibrations ll
Monoatomic Chain
The simplest crystal is the one dimensional chain of identical atoms with identical masses M connected by identical springs of
spring constant K.
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Equating the total force to the right, to the product of mass and acceleration we have,
The total force = Force to the right – Force to the left
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Equation of atom for nth atom
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Transverse and Longitudinal
Phase Velocity and Group Velocity
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Lattice Vibration IV
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Phonons
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Phonon Momentum
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Transverse mode
In real crystals, these two transverse modes are degenerate on only in special high-symmetry directions.
In general, for directions of propagation, each of these two transverse modes and the one longitudinal mode all have different frequencies
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Lattice Vibration III
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Normal Mode
Diatomic molecules only have one stretching mode where the two atoms in a molecule vibrate with respect to each other
In the simplest approximation, we imagine that the atoms are attached to each other by a linear spring.
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In a normal mode, all of the atoms move with the same frequency.
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