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CML - Coggle Diagram

- - - - DEPENDS ON
        
        VOLUME OF THE SOLUTION /CONTAINER IS CONSTANT
        
        THEN DIRECTLY EXPRESSSIONS INVOLVE ONLY CHANGE IN CONCENTRATION TERM
        
        WHATEVER FORMUKAS WE LEARNED IN 12TH ONLY APLLICABLE TO THIS CASE
        
        VOLUME IS NOT CONSTANT
        
        PRACTICE PROBLEMS RELATED TO THIS CASE
      - THAT THE GENERALISED DEFINATIO N IS TERMS OF THE EXTENT OF THE REACTION ALWAYS WORKS
    - - based on the types
        
        consecutive
        
        steady state approximation
        
        condition
        
        incubation time
        
        max intermediate
        
        time at whcih this happens
        
        parallel
        
        reversible reactions or
        
        finding the equilibrium concentrations
      - we assume all at constant volume and first order reaction mostly
- - - - bonds between carbon and
    - - neutral atom method
        
        assume equal sharing
        
        anionic ligands radical
        
        zero oxidation state metal
        
        keep track of the overall charge on the molecule
        
        -ve add electrons
      - oxidation state method
        
        oxidation state metal needed
        
        anionic ligand -ve means two electron
        
        purely ionic
      - neutral ligands no problem
        
        focus on lonepairs
      - bridging ligands
        
        3c-3e
        
        3c-2e
      - zero electron ligands boron then it accepts
      - applications
        
        metal metal bonds if 18e rule obeyed
        
        predicting reactions oxidisng / reducing
        
        predict the structure and other thigs
- - - - 2D
        
        FISHER PROJECTION
        
        TWO GROUPS AT THE TERMINAL MUST BE GOING AWAY FROM YOU
        
        ALL THE BONDS MUST BE ECLIPSED CONFIG
        
        WHEN CONVERTING FISHER TO THE SAWHORSE BE CAREFUL THAT THE TWO GROUPS AWAY AND THAT THE BONDS MUST BE ECLIPSED
        
        SAWHORSE
        
        SEE ALONG THE CC BOND OBLIQUELY
        
        NEWMANN PROJECTION
        
        LOOK ALONG THE C-C BOND ORTHOGRAPHICALLY
      - 3D
        
        WEDGE DASH
        
        KEEP MIND THE ECLIPSED AND THE STAGGERED CONFIGRATIONS ALONG THE BONDS
        
        KEEP IN MIND THAT ITS NOT ARBITRAY THAT YOU DRAW THE WEGDE ,DASH ,TWO BONDS IN PLANE YOU MUST KEEP SOMEWHAT THE TETRAHEDRAL SHAPE
    - - MOLECULAR FORMULA
        
        BOND CONNECTIVITY
        
        NON SUPERIMPOSABLE MIRROR IMAGES OR NOT
        
        OPTICALLY ACTIVE OR NOT
        
        BOND ROTATIONS
  - - - reactivity
        
        diene
        
        s cis vs s trans
        
        cyclic vs acyclic
        
        subsitiuents at 1 vs at 2
        
        1 > 2
        
        EDG MORE
        
        planarity
        
        outisde vs inside subs
        
        outside more reactive
        
        diene
        
        EWG
        
        THOSE with resonance better than the inductive only ones
      - regioselectivity
        
        partial charges
        
        focus on where the nu or electrphile will attack