Pollution
Properties of pollutants
General strategies to control pollution
Effects of environmental features
Persistence: This is a measure of time that they remain in the atmosphere
Toxicity How dangerous the mineral is
Density: This will affect its dispersal. Denser requires more energy to remain suspended and deposited earlier
Synergism: this involves 2 or more pollutants having their effects interacting with each other
Energy form: The different pollutnats that are energy forms such as noise
State of matter: Whether or not the material is actually worth mining
Factors affecting degradation
Factors affecting dispersal
Oxygen: Involved in aerobic bacterial decomposition in sewage. Oxidation of sulfide ores causing sulfur dioxide.
pH: pH can affect the solubility of substances. Many heavy metals such as lead are more soluble and therefore mobile under acidic conditions
Light levels: Light can provide the activation energy that drives chemical reactions for example photochemical smogs
Pollutant interactions: The behaviour of a pollutant may be affects by the presence of other pollunants such as:
- Interactions of NOx and hydrocarbons in photochemical smogs.
- Combined affects of phosphates and nitrates in eutrophication
Temperature: Most chemical reactions occur more rapidly if the temperature is higher. So this may lead to deoxygenated water
Temperature inversions The higher temperatures above, the higher the pollutants can be allowed to go higher and dispersed.
The presence of adsorbent materials: Pollutants may absorb onto other materials such as radioactive calcium from chernobyl was absorbed by rain and then absorbed by soil
Wind: The velocity and direction of air and water currents will affect how they are dispersed
Critical group monitoring: Risk of public exposure to pollutants. It assesses the risk to members of public at risk. If the risk to the public is too severe, then they will reduce the exposure to the pollutant
Emission control strategies
- Making sure that they are in a good spot
Critical pathway analysis Predicting the movement of potential pollutants in the environment to assess the severity and location of a pollutant.
Control of emission location: The severity of pollution is affected by the location where the discharges are released/ Although the emission location is not normally determined by the location of the source
Control of emission timing Emissions released when the tide is going in, will result in the pollutant being carried upstream and vice versa. In addition during a temperature inversion, you could stop the emissions as they would not disperse
Smoke and smoke smogs
Smoke is made from atmospheric particulates produced from incomplete combustion. Smoke is categorised by particulate size. Toxic chemicals such as fluorides, aluminium, lead, acids and organic compounds. Smoke can act synergistically with other pollutants
Smoke smogs
Effects on smoke pollution
Properties of control
Selection of method: There are several general approaches to fixing this behaviour
Precautionary Principle This is researching the wastes danger before its released
The polluter pays principle There is an obligation to reduce pollutants. If the costs are too high, then they wont stop
On other organisms: Reduced photosynthesis as smoke blocks light. Also some minerals in smoke are toxic
Smoke in the stratosphere can also deplete the ozone layer.
On humans: this can cause respiratory problems
Fog tends to form when moist air is cooled until it reaches its dew point. This makes the temperature inversions more likely
Smoke has a very high albedo so the temperature inversion can last for long periods of time, allowing pollutant levels to rise to a large levels
Made by smoke+smog
Control measures
Transport sources: Diesel particulate filters (DPF) fitted in exhaust pipes of diesel engines trap up to 80% of smoke particles
Electrostatic precipitators Effleunt gasses are passed through a chamber with many charged wires or plates. The smoke particulates are suspended here and fall into 'fly ash'
Domestic sources: Increased use of fuels that do not produce smoke
Cyclone separators: Essentially a vacuum. Takes in smoke and spins it until the solids suspend themselves
Legislation Clean air act (1956). This restricted the use of fuels that produce smoke
Coal treatment: Heating coal allows the tar that causes smoke to be drained off
Bag filters: remove smoke particulates by trapping them in a cloth
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Photochemical smogs
Effects
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Sources of photochemical smogs
NOx are released from exhaust gasses. In the presence of sunlight, other pollutants are more toxic which leads to a much more toxic secondary pollutant called Peroxyacetyl nitrates(PANS). Also has ozone
Tropospheric ozone contributes to the production of PANS but is also toxic itself.
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NOx increased the risk of respiratory issues
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PANS are toxic at high concentrations, They cause eye irritation