Ch. 15 Quantum Theory

The Photoelectric Effect E=hf

Quantization- the natural world is granular rather than smoothly continous

Quantum- any elemental particle that makes up matter or carries energy

The photoelectric effect is a model for how matter radiates

hypothesized by Max Plank in 1900s

warm bodies emit radiant energy in individual budles called quanta

energy in each quantum is proportional to the frequency of radiation

Frequency of light

low frequency light does not eject electrons

high frequency light does eject electrons

Einstein viewed light as a stream of particles, photons interact with matter one at a time, and high energy photons dislodge electrons from certain metals

Types of Light Excitation

What is Fluorescence?

material excited by ultraviolet light emit visible light upon de-excitation

How do fluorescent lamps work?

Electrons are emitted from filaments and strikes mercury that then releases an UV photon that strikes the inner phosphorus lining inside the lamp and produce a white lamp

What is incandescence?

frequency of radiation emitted from a hot body

peak frequency is proportional to the temperature

Electron diffraction

What are lasers?

Lasers are coherent beam of light rays that have the same frequency and are in phase

Incoherent light- light waves out of phase and different frequencies)

Monochromatic light- same light wave frequency but are out of phase

LASERS ARE NOT A SOURCE OF ENERGY

According to Louise de Broglie- a particles wavelength is related to their momentum; wavelength =h/mv

electron waves orbiting a nucleus form standing waves

Wave-Particle Duality

A photon acts like a particle when emitted by an atom, but behaves like a wave when traveling

uncertainty principle (only applies to quantum mechanics) states that at atomic an subatomic realm, position and motion are uncertain to predict

uncertainties in measurement of momentum and position when multiplied must be equal to or greater than planks constant

uncertainties in the measurements of time and energy when multiplied must be equal to or greater than planks constant

correspondence theory- introduced by Niels Bohr that states the new theory and old must correspond

complementary- accepting alternate explanations for natural phenomena

What is phosphorescence?

electrons are excited and "bounce" or are de-excited from traveling between energy levels

electrons getting excited and when getting de-excited, the electron gets "stuck" at an energy level then returns to its ground state.

electrons getting excited and when getting de-excited, the electron gets "stuck" at an energy level then returns to its ground state.