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Theoretical Molecular Biophysics Part 3. Reaction Kinetics (6.Formal…
Theoretical Molecular Biophysics
Part 3. Reaction Kinetics
6.Formal kinetics
Elementary chemical reaction
(Recersible, in equelibrium)
Reaction variable and rate
Stoichiometric (educt and product)
Order of reaction
Zero order reactions
Regardless of the concentration
First order reactions
Decay of the exites state
Obey the equations A+B->...
Exiton-exiton anihilation in light-harvesting photosynthetic complex
Dynamical equilibrium
1st order reaction+back reaction
5.Competiing reactions
If species decays via separate independent channels
Radiationless transition
Cosecutive reactions
Chain of two 1st order reactions
7.Enzymatic catalysis
Eigen value
Michaelis constant
Micaelis-Menten equation
Stationary concentration of ES complex
Reactions in solutions
Reactants approach each other by deffusion in the solution forming reactive complex
Kinetic Thheory - Focker-Plank equation
8.Kramer theory
Despersive kinetics