1997, Fe-porphyrin first introuduced in photoreduction of CO2
no PS
Co,Fe porphyrin
1999, Fe-porphyrin (63) Co-porphyrin (62)
p-terphenyl as PS
Co,Fe phthalocyanines and corroles
2000, FePC64, CoPC65 not higher than porphyrin analogues
2001, Co66, Fe67,68-corroles comparable to porphyrins
2014, Fe-porphyrin-o-OH 14 higher selectivity of CO (85%) than FeP, no PS, TONco=30
introduce -OH
stabilized the CO2 by htdrogen bonding
accelerate cleacage of CO bond
2014, Fe-porphyrin-o-OH
[Ir(bpy)3]+ as PS
2014, Fe-porphyrin-o-OH
organic compound as PS
TON co=140, selectivity=93%
selectivity~100%
2017, Fe-p-TNT
Fe polypyridines and carboxyl complexes
Fe(bpy)(CO)3 is the active species
Fe3(CO)12+Ru(bpy)3+bpy
2016, Fe3(CO)12+Ru(bpy)3
2016, Fe-cat., Cu-PS, selectivity 78%, TONco>270
2016, Feqpy+Ru(bpy)3, TONco=1879, selectivity=97%
2016, Feqpy+organic 48, TONco=1365, selectivity=92%
2016, Fe cyclopentadienone 43 + Ir as PS
2016, Fe cyclopentadienone 44, no PS
TONco=421, TONformate<40
TONco=596, selectivity~100
from organic synrhesis to CO2 reduction