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1997, Fe-porphyrin first introuduced in photoreduction of CO2 (Co,Fe…
1997, Fe-porphyrin first introuduced in photoreduction of CO2
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Co,Fe porphyrin
1999, Fe-porphyrin (63) Co-porphyrin (62)
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Co,Fe phthalocyanines and corroles
2000, FePC64, CoPC65 not higher than porphyrin analogues
2001, Co66, Fe67,68-corroles comparable to porphyrins
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2014, Fe-porphyrin-o-OH
[Ir(bpy)3]+ as PS
TON co=140, selectivity=93%
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2016, Fe cyclopentadienone 43 + Ir as PS
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2016, Fe cyclopentadienone 44, no PS
TONco=596, selectivity~100
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2014, Fe-porphyrin-o-OH 14 higher selectivity of CO (85%) than FeP, no PS, TONco=30
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2016, Fe-cat., Cu-PS, selectivity 78%, TONco>270
2016, Feqpy+Ru(bpy)3, TONco=1879, selectivity=97%
2016, Feqpy+organic 48, TONco=1365, selectivity=92%