4-Evidence of abundances from spectral lines

Star light has absorption lines

Study of these can find photospheric composition

Optical depth maths

BB radiation

Lines are generally superimposed on a bb spectrum

Absorption Spectra

Depend on temperature and pressure in the stellar atmosphere

hotter temp = greater mean thermal energy

break up of molecules, then ionization of atoms

Will a line be seen?

Hottest stars have opaque atmosphere

UV absorbed by earths atmosphere

Strength depends on 3 things

how much the element is in the right ionization state

Amount of element which is present

cross-section for absorption, strength of transition probability

Equivalent width

width at which 100% absorption occupies the same area as the observed line

relationship between EW and number of absorbing atoms is curve of growth

Maths:

Sources of broadening

Local

Dopper

Natural

Pressure

Non-Local

opacity broadening

rotational

thermal motion along line of site

gaussian

due to heisenburg uncertainty

lorentzian

radiation affected by nearby particles

lorentzian

speeds described by maxwell-boltzmann

linear stark

quadratic stark

only affects atoms/ions with perm EDM

Broadening proportional to E field strength

Strongly effects HI lines in hot stars

atoms/ions perturbed by passing electrons

proportional to square of E field strength

Affects most lines in hot stars

Van der Waals

Zeeman

Neutral atoms with momentary dipoles perturb eachother

E cubed shift

common in cooler stars

Lines split by magnetic fields

splitting proportional to square of wavelength

effect varies

important in giants and supergiants