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CHEMISTRY (Reactions (Carbonyl chemistry and reactions of organic…
CHEMISTRY
Reactions
Carbonyl chemistry and reactions of organic compounds
Electrophilic aromatic substitution
Conjugate addition
Nucleophilic aromatic substitution
Alkylation of enolates
Reactions of enolates with carbonyl compounds
Nucleophilic addition
Strecker synthesis
Grignard reaction
Organolithium reactions
Metal halogen exchange
Formation of grignard reagents
Carboxylic acid reduction
Acetal formation
Alcohol to ether mechanism
Reductive amination
Imine formation
CN to carboxylic acid mechanism
Leaving group ability
Primary amines
Hemi-acetal formation
Nucleophilic acyl substitution
Delocalisation (electrons) and acidity, delocalised charge and lone pairs
Electron withdrawing effect
Ranking of nucleophilicity
Hard and soft nucleophiles/electrophiles
Tautomer stability
Forming enols
Acidity and where the double bond goes
Optical activity and racemisation
Isomerisation mechanism
Phenol synthesis
Friedel-Crafts acylation
Oxidation of the methyl group
Formation of acylium ion
Mono-substitution
Thionyl chloride
Reduction synthesis of alcohol from a ketone using MeLi
Ether synthesis
Halogenation of aldehydes and ketones
Alkylation in the presence of a base
Alpha-bromination
Idoform reaction
Sulfonation
Wheland intermediates
Resonance stabilised structures
Acidic cleavage of ethers
Reactions of coordination complexes
Electronic spectra and reactions of coordination complexes
Organometallic chemistry
Trans-effect
Substitution mechanisms
Labile and inert complexes and ligands
Cone angle
Rate of substitution
Ligand field activation energy
Electron counting
18 electron rule
Hapticity
CO stretching frequency
Backbonding
Bridging CO ligands
Reductive elimination
β-hydride elimination
Preparing simple metal carbonyls
Difference in IR wavenumbers
Pi-acid ligand
Inductive effect
Rate of exchange
Catalysis
Catalysis and materials
Chemical compounds
Coordination compounds
Thermodynamics of complex formation
Basics of coordination chemistry
Nomenclature
Isomers
Electronic structure of coordination complexes
Naming coordination complexes
Isomers of coordination complexes
Identifying coordination complex structure
Crystal field splitting theory
Orbital splitting diagrams
Octahedral, tetrahedral, tetragonal, square planar etc.
Degenerate orbitals
Field ligand strength
π-acceptors and π-donors
High spin and low spin electrons
Mean pairing energy
Ligand field splitting energy
Magnetic moment
Diamagnetic/paragmagnetic
Ligand field theory
π-bonding
π-bonding ability and spectrochemical series
Bonding
Matter
Phases
Energy