Bioenergetic's and important molecules

Bioenergetics: Is the flow of energy through living organisms

This energy is used to overcome the second law of thermodynamics

Living systems become more ordered, Living systems use energy to overcome local entropy

Disorder within the surrounding increases

Entropy within the universe increases

For organisms to grow, cells need energy, precursor metabolites and reducing power. Metabolism is: All teh chemical reactions going on in an organism

Use of food to produce energy

Use of food to create building blocks

Use of energy to run cellular processes

Use of building blocks and energy to create larger, more complex molecules

aseries of enxymatic reactions

Catabolism: Reaction breakdown the foodstuffs that are taken is, These reaction realease energy, simple compounds and reducing power.

Anabolism: Biosynthetic reactions used by a cell to make new material and larger molecules, These reactions use energy, simple compounds and the reducing power released in catabolism

Catabolism:

Degradative

Oxidative

Energy yielding

Uses a variety of starting materials

Has well defined products

Uses NAD+ or NADP+

Anabolism:

Synthetic

Reductive

Energy requiring

Has well defined starting materials

Has a variety of products

Uses NADPH

When looking at Energy changes we need to measure:

Internal Energy: (E) Total energy of the system

Enthalpy: (H) Heat content

Entropy: (S) Degree of disorder

Gibbs Free Energy: (G) energy available to do work

Temperature: (T) Temperature of the system in Kelvin

Free energy is related to the total chemical energy of the system and hence to the chemical stability of the system

If Free Energy is high we have a potentially unstable system and the system will tend to go to a lower free energy state - Likely to be spontaneous

If change in free energy is zero, the system is at equilibrium, To shift a system from equilibrium energy will need to be put in.

Exergonic: Release energy

Endergonic: Require energy

Living organisms maintain a steady state. This is not an equilibrium.

Enzymes change the rate of reaction but not the overall energy potential - They lower activation energy by providing a favourable pathway.

ATP: Acts as an energy carrier - When hydrolysed, energy is released

NAD+ and NADP+ these can be oxidised - accept two electrons and a proton

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NADH and NADPH these can be reduced

FAD has similar functions to NAD+, it is an electron carrier