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CARBOHYDRATE (monosaccharide (1) (stereochemistry (multiple chiral centers…
CARBOHYDRATE
monosaccharide (1)
cyclic structure
hemiketal (OH =1)
hemiacetal (OH=1)
pyranose rings (6C)
furanose rings (5C)
anomeric C
reactions
mutarotation
oxidation
reduction
isomerization
esterification
glycoside formation
stereochemistry
multiple chiral centers
enantiomer
chirality
diastereomer
stereoisomer
epimer
isomer
derivatives
acids and lactones
alcoholic sugars
deoxy sugars
glycosides
phosphate sugars
amino sugars
chiral
oligosaccharide (2-20)
types glycans
n-linked
o-linked
diversity glycoproteins
membrane protein
hormone
immunoglobulin
enzyme
functions
glycolipid
(provide energy)
glycoprotein
(immune cell recognition)
glycolipid determine blood group
n-acetyle (A antigen)
galactose (B antigen)
carbohydrate
functions
energy storing molecules
structural components
energy source
derivative molecular biology
classification
disaccharide (2)
definition
types bond
maltose a(1-4) glycosidic bond
sucrose a(1-2) glycosidic bond
lactose B(1-4) glycosidic bond
cellobiose B(1-4) glycosidic bond
polysaccharide (>20)
homopolysaccharide
cellulose
chitin
glycogen
amylopectin
starch
a-amylose
amylopectin
heteropolysaccharide
glycosaminoglycan
peptidoglycan
comparison
gram +
gram -