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Real Gases (“ideal” liquid Capture (Molecules have finite mass and finite…
Real Gases
“ideal” liquid
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Constant T:
Remember this equation: it also
works quite well for real liquids!
ideal gas
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Limited accuracy
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You need correction when H, S and PVT-correlations deviate significantly from ideal
gas correlations
IF one of these quantities deviates, usually all three do.
Method: check PVT (because that is simple)
If PVT data follows ideal gas laws, you can assume that enthalpy and entropy also will follow ideal gas correlations
Real gases are actually not that common: don’t waste time on real gas calculations
when it is not necessary
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Real fluids (gas, liquids or solids)
Molecules have finite volume (and cannot occupy the same space)
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Real gases
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Which relationships do NOT work any more for a real gas:
PV=RT
Polytropic relationships
u=u(T), h=h(T)
Q (or W) =CpΔT
v/d Waals equation
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Phase change and 2-phase region are NOT captured in v/d Waals equation, even though the equation gives a result!
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Method 0
Low pressure, low density and high temperature gases are always ideal
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Compressibility factor
Z->1 when Pr->0
Z->1 when Tr-> Tboyle (~ 2,5 )
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