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ENERGETICS (Hess's Law (Standard enthalpy change of Formation (Example…
ENERGETICS
Hess's Law
Example of question
Use the following enthalpy change data:
Reaction 1 2H2(g)+O2(g) → 2H2O(l) ΔH1=−572kJmol−1
Reaction 2 2H2(g)+O2(g) → 2H2O(g) ΔH2=−484kJmol−1
to work out the enthalpy change for the process:
H2O(l) → H2O(g)
Method 1 (Enthalpy Cycle)
- Draw the diagram of the reaction (the enthalpy cycle)
- Look at the direction of the formation of the main equation as shown below:
- Then, solve the question by using the cycle as your guide
- The same direction, add,different direction, subtract
Method 2 (Manupilating Equation)
- Look at the equation given:
Reaction 1 2H2(g)+O2(g) → 2H2O(l) ΔH1=−572kJmol−1
Reaction 2 2H2(g)+O2(g) → 2H2O(g) ΔH2=−484kJmol−1
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Definition
The enthalpy change accompanying a chemical reaction is independent of the pathway between initial and final states
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Average bond enthalpy: the energy needed to break one mole of bonds in gaseous molecules under standard conditions averaged over similar compound.
More atoms in a molecule, more energy requires to break the bond
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Bond formed (Exothermic Reaction) - Helps in maintaining relatively high temperature of stratosphere by producing heat