Chapter 5 (Ellie Ward)

Models of the Electron

Quantum Mechanical Model

The Principles and rules

Electron Configurations

4s 4p 4d 4t

5s 5p 4d 5t

3s 3p 3d

6s 6p 6d

2s 2p

7s 7p

1s

Thomson's: Electrons stuck in a sphere

Bohr: Electron "orbit" the nucleus in specific paths like the planets orbit the sun

Today's Model: Electron Cloud Model

Aufbau Principle

Pauli Exclusion Principle

Hund's Rule

Heisenberg Uncertainty Principle

One electron enters each orbital until all the orbitals contain one electron with the same spin direction

The rule that electrons occupy the orbitals of lowest energy first

An atomic orbital may describe at most two electrons, each with opposite spin direction

It is impossible to know exactly both the velocity and the position of a particle at the same time

Electromagnetic spectrum

Series of waves

Ground State

Light is energy

Added Energy

Light energy given off in waves // Light particles are called photons

Visible light (Spectrum) //Low Energy-R O Y G B I P-High Energy

High Frequency/Small Wavelength - Gamma Rays

Low Frequency/Big Wavelength - Radio Waves

Electron in the lowest possible energy level.

Electron Jumps from High
To Low State

Atomic Emission Spectra

Light emitted as electron jumps. // The Bigger the jump, the
more light is emitted.

When Atoms absorb energy, electrons move into higher energy levels. They will then lose energy and emit light when they return to lower energy levels.

tells how likely it is to find an electron in
various locations around the nucleus.

Atomic Orbitals

Principal Energy Levels

Maximum electrons for each level

n=1//1 sublevel//1s (1 orbital)

n=4//4 Sublevels//4s (1 orbital), 4p (3 orbitals), 4d (5 orbitals), 4f (7 orbitals)

n=2//2 Sublevels//2s (1 orbital), 2p (3 orbitals)

n=3//3 Sublevels//3s (1 orbital), 3p (3 orbitals), 3d (5 orbitals)

n2 = 8

n3 = 18

n1 = 2

n4 = 32