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Bonding - Verrel (Ionic and covalent bonds and structures (Giant ionic…
Bonding - Verrel
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Polarity
Covalent compounds are formed between two non metals (on the far right of the periodic table). The bonds can be predicted to be covalent by calculating electronegativity difference between the atoms - if it is less than 1.5 it is said to be covalent.
The relative polarity of a bond can be predicted through the electronegativity difference - a value between 0 and 0.2 is said to be non polar covalent, and from 0.3 to 1.4 it is a polar covalent bond
A polar covalent bond is one in which there is an electrostatic attraction between shared pair(s) of electrons and 2 positive nuclei, yet the electrons are shifted towards one atom (due to a greater effective charge and small atomic radius), creating a polar bond.
A non polar covalent bond is one in which there is an electrostatic attraction between shared pair(s) of electrons and 2 positive nuclei and the electrons somewhat equally shared between them.
An ionic bond forms when a metal transfers its electrons to a non metal atom, in order to gain a stable noble gas configuration. They form giant ionic lattices of repeated oppositely charged ions.
Dative covalent bonds, also known as coordinate bonds, are covalent bonds where the shared pair of electrons come from the same atom i.e in NH4+ - the nitrogen donates its lone pair to a H+ ion making it positive.
We know ions exist as a dissolved solution of an ionic compound can carry an electric current across it, whereas the solvent (water) does not do this on its own. This requires the solution to have positive and negative particles that can transfer electrons, and these are what we call ions.
Polarisation in ions refers to how highly charged ions can distort the electron clouds of the other ions. For example, a highly charged cation may pull some electrons from the anion closer to itself. This change results in the molecule having some covalent properties - this is known as intermediate bonding.
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