Chapter 11: Opioids

Narcotic analgesics

Features

produce a sense of euphoria

create a sense of relaxation and sleep

high doses --> coma and death (because of respiratory infection; inhibits brain stem center that controls breathing reflex)

TYPES

opium: extract of poppy plant

opiate: substances derived from the poppy (i.e. morphine)

opioid: includes opiates, semi-synthetics (heroin), synthetics (fentanyl), and endogenous peptides (endorphins)

Heroin: first marketed by Bayer (1898) as a NONADDICTING substitute for codeine to control coughs

Levels of narcotics

Natural narcotics

opium

morphine

codeine

thebaine

Semisynthetic narcotics

From morphine

hydromorphone (dilaudid)

From thebaine

etorphine

Totally synthetic narcotics

pentazocine (Talwin)

meperidine (demerol)

FENTANYL

methadone (dolophine)

LAAM

Propoxyphene (Darvon)

Endogenous opioids

enkephalins

ENDORPHINS

dynorphins

endomorphines

heroin

oxycodone (percodan)

HEROIN STRUCTURE: 2 acetyl groups added to morphine

more lipid soluble (readily absorbed)

converted to morphine in brain

2-4x stronger than morphine when delivered IV

PO: heroin and morphine are equipotent

4 components of opioid intoxication (route of rapid admin-dependent (IV))

1) Rush: wave of euphoria within 10 seconds

2) High: general feeling of well-being (last for hours after rush)

3) Nod: overlaps with high, state of escape from reality

4) Being straight: no longer experiencing rush, high, or nod (NOT experiencing withdrawal yet)

withdrawal occurs 8 hours after taking the drug

reduce pain WITHOUT producing unconsciousness (not an anaesthetic)

Adverse effects of opioids

dysphoria, restlessness and anxiety, nausea and vomiting (affects the area postrema in the brainstem)

high doses, sedative effects --> unconsciousness

body temp and blood pressure fall, pupils become constricted (small pupils), respiratory failure

significant effects on GI tract: opioid induced constipation

Opioid Rectors and Endogenous Neuropeptides

Receptors

4 subtypes: m, S, K, NOP-R (distinct distributions in the brain and spinal cord --> mediates a wide variety of effects)

opioids exert nearly all of their clinically relevant actions through stimulation of m-receptor

m receptor has high affinity for morphine and related drugs

mediates the reinforcing and rewarding effects of opioids

m-receptor KO mice:

DO NOT self admin opioids

do not exhibit conditioned place preference for opiodis

do not show signs of physical dependence

analgesia, respiratory depression, and constipation are ABSENT

Location of m-receptors reflect the effect of opioids

ANALGESIA: medial thalamus, periaqueductal gray, median raphe, locus coeruleus, spinal cord

POSITIVE REINFORCEMENT: VTA, nucleus accumbens

CARDIOVASCULAR AND RESPIRATORY DEPRESSION, COUGH CONTROL, NAUSE: brainstem

All opioid receptors are GPCRs

Gi: inhibits adenylyl cyclase

reduction in cAMP

important in understanding the CHRONIC effects of opioids: tolerance, dependence, withdrawal

K+ channel opening, Ca++ channel closing

ion channel effects are responsible for ANALGESIC effects

Endogenous opioids: neuropeptides

released by neurons at nerve terminal via Ca++ dependent exocytosis

not synthesized in the nerve terminals - they are PEPTIDES so they're synthesized in ribosomes

most synthesis occurs in rough ER

secretory granules in Golgi (filled with peptide) bud off and are transmitted to nerve terminal

Can be coexpressed with neurotransmitters

violates Dale's Principal that states only 1 NT per synaptic vesicle

4 precursor peptides are processed into smaller active opioids

Prodynorphin --> dynorphin

*Pro-opiomelanocortin (POMC) --> beta-endorphin

Proenkephalin --> enkephalin

Proniciceptin/orphanin FQ --> nociceptin

Opioids and neuronal inhibition

Postsynaptic inhibition: receptors activate a G protein that opens K+ channels

Axoaxonic inhibition: receptors activate G proteins that close Ca++ channel

Presynaptic autoreceptors: activate G proteins and reduce release of a co-localized NT

Opioids and Pain

opioids drug bind to opioid receptors and mimic the INHIBITORY action of endogenous opioids at MANY STAGES of pain transmission

Regulate pain in 3 ways

Within spinal cord

descending pathways from PAG

higher brain sites (cortical areas): influences the emotional and hormonal aspects of the pain response

inhibit the projection neuron (projection neuron carries pain signal to higher brain areas)

treatment of chronic pain with electrical stimulation of the PAG (PAG has a lot of endogenous opioids and m receptors)

tolerance occurs with repeated stimulation

stimulation of PAG caused cross-tolerance with opioids

an opioid-like substance must be released

Stimulation of PAG --> activation of 2 descending pathways that inhibit pain signal

locus coeruleus --> spinal cord

raphe nuclei --> spinal cord

Descending pain regulation in PAG

opioids REMOVE inhibitory GABA brake on descending projection TO raphe/LC

opioid binds to m receptor on GABAergic interneurons --> releases projection neuron to Raphe/LC (freeing inhibition of GABA)

Raphe: 5-HT neurons descend into spinal cord and inhibit firing of ascending pain projection signal

Reinforcement, Tolerance, Dependence

Reinforcement

Opioids are reinforcing

Mesolimbic DA pathway and opioid reinforcement

opoids injected into the VTA increase DA cell firing

increases release of DA within the NAcc

BUT lesioning of DA neurons DOES NOT ABOLISH heroin self-admin

opioids increase VTA cell firing by INHIBITING inhibitory GABA projections

leads to increased firing and greater DA release in the NAcc

in animal studies, ACUTE pretreatment with opioids LOWER the threshold ICSS (enhances brain reward system)

Dependence

chronic opioid use --> physical dependence

neuroadaptive state: in response to longterm occupation of opioid receptors

when drug is no longer present, cell function returns to normal and OVERSHOOTS basal levels

withdrawal symptoms: rebound hyperactivity

Severity of withdrawal varies with specific drug and ROI

Heroin (IV): peak is 48-96 hours after last use

withdrawal is complete in 7-10 days

at the point when abstinence signs end, user is considered "detoxified"

Methadone (PO): gradual increase over several days and gradual decrease over several weeks (TAKES LONGER TO RECOVER BUT WITHDRAWAL SYMPTOMS ARE MORE MODERATE)

Himmelsbach: Theoretical model of opioid tolerance and dependence

nervous system ADAPTS to disturbing presence of drug --> tolerance

If drug is withdrawn, the adaptive mechanism continues to function, causing rebound physiological effects (withdrawal symptoms)

Dealing with withdrawal: NE a2 autoreceptor

withdrawal activates NE system

symptoms

low energy, irritability, anxiety, agitation, insomnia

hot and cold sweats, goose flesh

abdominal cramping, nausea, vomiting, diarrhea

a2-agonists such as clonidine treat symptoms

Neuronal basis for tolerance/dependence: glutamate and NMDA receptor

tolerance to chronic morphine is reduced by non-competitive NMDA antagonist

increased opioid-induced PKC activation may phosphorylate NMDA receptor

enhances channel function

makes it easier to activate and contribute to tolerance via activation of nitric oxide synthase

Medication-Assisted treatment for opioid addiction

Methadone maintenance (PO): opioid agonist

little/no euphoria occurs PO

relieves craving

requires daily supervised admin

cross-dependence with heroin --> prevents severe withdrawal symptoms

normal euphoric effects of heroin are reduced, reducing likelihood of relapse

Cross tolerance becomes a PROBLEM when patients need analgesia in the ER

Buprenorphine: partial agonist

weaker effects than methadone and longer duration

doses are 1-3 times/week because effects are longer

Suboxone: buprenorphine + naloxone (opioid antagonist)

when taken PO, buprenorphine is absorbed but the naloxone is NOT

BUT, if crushed and injected, naloxone BLOCKS buprenorphine's euphoric effects

HEROIN ADDICTION TREATMENT (HAT)

supervised injectable heroin (SIH)

designed to help severely opioid-dependent people who are resistant to MAT

provide heroin at very specific times and very specific doses to try to sustain that stability and withdrawal symptoms

naltrexone: antagonist

longer duration of action than naloxone

effective when taken PO

few side effects

cravings are NOT eliminated

must detox first because naltrexone causes severe withdrawal symptoms

vivitrol: injectable, extended release naltrexone (given once a month)

Kratom: not FDA approved

substitute for opioid, reduces withdrawal symptoms

Acute opioid overdose: treat with naloxone (opioid antagonist)