Subsurface water and clay mineral
formation during the early history of Mars

Controls on Clay Mineralogy

Open System

Closed System

Clay Distribution and Diversity

Figure 1

Crustal Clays

Sedimentary Clays

Clays in Stratigraphies

Timelines for Martian environments (Figure 4)

Conclusions + Connections to previous papers

Occur in subsurface waters

Closed =Water is closed off from the Martian afmosphere

Typically low water-rock ratio (W/R <1)

Ion transport is minimal, so elemental amounts remain constant

Products: Iron(ii)/Magnesium smectits, chlorite and serpentine

Nearer to the surface

fluids are in contact with the Martian atmosphere

Water to rock ratios:

Higher (W/R > 1)

Low (W/R < 1)

More ion transport = changes element amounts/composition

Residual rock (Rock that is not transported) is aluminium rich

Transported rock generate Fe/Mg smectite, jarosite & silica formation

Olivine is mostly what dissolves

Depleting the abundances of Fe/Mg smectite formation

amorphous products & salt form coatings

Map of clay distribution and diversity on Mars

Highlights the 3 different types of clays superposed on a map of Mars

Fe/Mg smectite and chlorite make up 78% and 39% (respectively) of crustal clays

Associated with craters

Either the result of crater impact (heat initiate hydrothermal systems)

CLAY MINEROLOGY

Can be used to model hydrothermal systems during Noachian/Hesperian periods

Through clay formation/diversity, we can understand the Martian hydrosphere

Or were pre-existing, but were excavated by crater impact

These materials placed as crater 'ejecta' are found ~5-10km deep in the craters

Clays detected in fluvial basins & lakes

Unlike crustal clays, hydrated silicates have not been detected

sedimentary clay composition varies depending on the fluvial system

it is not possible to determine whether sedimentary clays were transported to their current location (allocthonous) or formed there (autochthonous)

Occur in high-standing topography

Cannot be explicitly defind as crustal or sedimentary

Eg: Al clays that overly Fe and Mg clays

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a. Presence of a Pre-noachian era magnetic field

The physiochemical conditions on Mars that led to Fe and Mg clay formation imply the presence of Hydrothermal systems, direct precipitation, and subserface liquid waters throughout Mars' history

This links to the Baker paper, which explored Martian landforms due to the presence of water during various (Noachian, Hesperian and Amazonian eras)

This, in tandem with the Christiansen paper, paints a vivid picture of the Martian landscape with respect to Mineralogy

b. large impact craters through the Noachian era

d. Changes in aqueous environments (that influence weathering and precipitation)

f. formations of various clays (w/ different compositions) during various time periods (owing to the processes above)

c. Volcanism through the Noachian & Hesperian eras

e. Valley networks & outflow channels that are responsible for sedimentary clay formation