Ionic Compounds

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Explain limitations of diagrams and models

Work out the empirical formula from models and diagrams

Identify ionic compounds from structures

Ionic compounds are neutral overall, but consists of positively charged ions called cations and negatively charged ions called anions.

Ionic substances form giant ionic lattices containing positive and negatively charged ions.

They have high melting and boiling points, and conduct electricity when melted or dissolved in water.

An ionic compound is a chemical compound composed of ions held together by electrostatic forces termed ionic bonding

Ionic compounds often form crystals when they are arranged in giant ionic lattices. The illustration shows part of a sodium chloride (NaCl) ionic lattice.

sodium chloride structure

Positively charged Na ions and negatively charged Cl ions

The empirical formula of a compound is the simplest whole number ratio of each type of atom in a compound

An empirical formula can be calculated from information about the mass of each element in a compound or from the percentage composition.

How to:

Start with the number of grams of each element, given in the problem.

Convert the mass of each element to moles using the molar mass from the periodic table.

Divide each mole value by the smallest number of moles calculated.

Round to the nearest whole number. This is the mole ratio of the elements and is.

Diagram+of+Molecular+and+Empirical+Formulas

Dot and Cross

Pros:

Cons:

Suggests electrons from different atoms are different

Does not show the structure formed

Shows how electrons are shared in bonds or lossed or gained

Ball and Stick

Pros:

Cons:

Shows the structure of a molecule

Show how many bonds there actually are

Shows that the atoms are 3D

Suggests bonds are physical "sticks"

Shows atoms too far apart from each other

Metallic Bonding

Pros:

Cons:

Shows lattice structure

Helps explain properties such as conductivity and malleability

Does not show that ions would be constantly vibrating

Doesn't show that the electrons move

3D Space Filled Model

Pros:

Cons:

3D space filled models are very useful to see the shapes of molecules or structures

They do not show how atoms are bonded

They do not allow all atoms to be seen

You cannot determine a formula from them

dot and cross

ball and stick

metallic bonding

space filled