Stress affecting equilibrium

Changing Concentration

Adding more reactants or removing products increases the collisions, changing equilibrium.

Changing the temperature

Removing Products

Adding Reactants

Equilibrium constant : The higher the K the more product

Equilibrium position

Endothermic reaction: In an endothermic reaction heat is a reactant and the equilibrium shifts in the direction in which heat is used up (right)

Exothermic reaction: In an exothermic reaction heat is a product and the equilibrium shifts in the direction in which heat is used up (left)

Endothermic reaction

Exothermic reaction

According to Le Chatelier's principle

New equilibrium position

Changing volume & pressure

More products are made to balance

Forward reaction rate increases

More collisions

Adding more reactants adds stress and upsets equilibrium

Increasing heat will result in the decrease of products

Pressure acts as stress on the equilibrium

Lowering heat will result in the decrease of products

Increased # of particles increases pressure

Boyle's law: decreasing volume increases pressure

results in a shift to the right and the production of more products

Adding Products

Adding catalyst to equilibrium position

results in a shift to the left and the conversion of products to reactants

Rahaf Labban 11A

so the gases will go to the side with less particles.

equilibrium shifted to the right

Lowering heat will result in the increase of products

Increasing heat will result in the increase of products

Lowering heat will result in a higher K

Increasing heat K will result in less K

Lowering heat will result in a lower K

Increasing heat will result in a higher K