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Energy Metabolism: Photosynthesis (Environmental and Internal Factors…
Energy Metabolism: Photosynthesis
Environmental and Internal Factors
Leaf Structure
Light
Quality of sunlight
colors of wavelengths
Quality of light
light intensity of brightness
Light Compensation Point
Duration of Sunlight
number of hours per day sunlight is available
Water
C4 Metabolism
Photorespiration
energy wasting process
C4 metabolism
"C4 Photosynthesis"
PEP carboxylase
Crassulacean Acid Metabolism
CAM
second metabolic adaption
improves conversation of water while permitting photosynthesis
Photosynthesis
The Light-Dependent Reactions
"thylakoid reactions"
water and light don't directly interact with CO2
Figure 10-6
Figure 10-7
The Nature of Light
Electromagnetic Radiation Spectrum
encompasses gamma rays, X-rays, ultraviolet etc.
Quanta
Photons
The Nature of Pigments
Figure 10-9
Pigment
any material that absorbs certain wavelengths
distinctive color
Chlorophyll a
absorbs only red and some blue light
lets most pass through
especially high-energy radiation
Activated
when a quanta is absorbed by a pigment
Ground State
Excited State
Accessory Pigments
strongly absorbes wavelengths not absorbed by chlorophyll a
broaded action spectrum
chlorophyll b
carotenoids
Resonance
allows chlorophyll b to absorb wavelengths
transfer energy to chlorophyll a for chemical reaction
Antenna Complex
entire 300 chlorophylls a and b
carotenoids and their proteins
Reaction Center
structure contains a pair od special molecules
chlorophyll a whose properties differ
Fluorescence
release of light by a pigment
Absorption Spectrum
graph
shows which wavelengths are strongly absorbed by pigments
Action Spectrum
shows which wavelengths are most effective
powering a photochemical process
Figure 10-12
Photosynthetic Unit
all pigments and carriers that work together are packed into a granule
Photosystem I
P700
absorb red light of 700nm
absorbed by membrane bound electron acceptor, Fx
Z Scheme
those with little chlorophyll b
Ferredoxin
located in the thylakoid membrane
small protein with an active site
two iron atoms bound to two sulfur atoms
Ferredoxin-NADP+ Reductase
reduces NADP+ to NADPH
Photosystem II
Plastocyanin
gets e- from
contains copper
donates an electron to the chlorophyll a of the PSI
now oxidized, but now needs an electron
Cytochrome B6/f Complex
receives e- from plastoquinone
Q
gets e- from
molecule of quinone
Phaeophytin
chlorophyll a molecule without a Mg atom
P680
Electron Transport Chain
the various electron carriers- to P700 in PSI
those in which chlorophyll b is almost equal to chlorophyll a
The Synthesis of ATP
Chemoiosmotic Phosphorylation
Grana
all thylakoids in one region form vesicles at the same spot
so they occur in sets
Frets
thylakoids that lie between grana
Stroma
Thylakoid Lumen
some of the enzymes and electron carriers of the photosystems are embedded in the membrane layer facing the lumen
Figure 10-16
Figure 10-15
Noncyclic Electron Transport
when electrons flow smoothly from water to NADPH
CF0-CF1 Complex
ATP Synthetase of chloroplast
CF0 is where proton channel is located
CF1 phosphorylates ADP to ATP
ATP Synthetase
Figure 10-17
Cyclic Electron Transport
without making extra NADPH
chloroplast make extra ATP
The Stroma Reactions
"dark reactions"
ATP and NADPH interact with carbon dioxide
Calvin/Benson Cycle (C3 Cycle)
conversion of CO2 to carbohydrate
Acceptor Molecule
ribose-1,5-biphosphate
RuBP
first step
reacts with CO2
3-phosphoglycerate
RuBP carboxylase
RUBISCO
3-phoglyceraldehyde
PGAL
phosphate comes off
carbon is now reduced and energized
1,3-diphosoglycerate
reduced by NADH
Anabolic Metabolism
Anabolism
Anabolic Reactions
Storage Compounds
Short term storage
Intermediate-term storage
Long-term storage
The Synthesis of Polysaccharides
Gluconeogenesis
anabolic synthesis of glucose
Dihydroxyacetone phosphate
Fructose-1,6-bisphate
Fructose-6-hosphate
Glucose-6-phosphate
Energy and Reducing Power
Energy Carriers
enters using photosynthesis
converts light energy to chemical energy
First theoretical way
Allow pigments to enter every reaction
Second theoretical way
Make smaller intermediates
Guanosine Triphosphate
cariies high-energy phosphate bonds
Reducing Power
Oxidized
atoms don't carry as many electrons as it could
Oxidation State
increases the positive charge
Reduced
when electrons are added to an atom
Reduction Reaction
reduces the positive charge
Oxidation Reaction
often contains a lot of oxygen
Reduced Compound
contain hydrogen
Reducing Power
to force electrons onto compounds
Oxidizing Agents
oxidize the material they react with
Reducing Agents
Redox Potential
Figure 10-3
Other Electron Carriers
Cytochromes
small proteins
contain a cofactor, heme
holds an iron atom
part of the chloroplast's thylakoid
Plastoquinones
bind two protons
hydrophobic
Plastocyanin
carries electrons of copper
doesn't travel far
Figure 10-3