Nitrogen cycle

Nitrogen fixation:

  • nitr i tes -> nitr a tes
  • N2 converted into NH4 (Ammonium)
  • can happen by lightning ~ ionising
  • only way organisms cab attain N2 is directly from atmosphere ~ called nitrogen fixating organisms
  • bacteria e.g rhizobium convert it to ammonium through metabolic process

Reservoir and Main Chemical forms

Biosphere

Lithosphere

Atmosphere

Hydrosphere

Oxides of Nitrogen

Nitrogen gas

Living organisms ~ DNA, proteins

Dead organic matter ~ proteins, they release ammonium compounds as they decompose

Soil ~ ammonium compounds, nitrites, nitrates

Rocks ~ minerals containing nitrogen

Dissolved nitrates and ammonium ions

Main processes

With living organisms

Without living organisms

Ionisation - processes such as lightning and meteor trails provide energy for atmospheric nitrogen and oxygen to react and produce oxides of nitogen

Denitrification - chemical reduction of nitrates in soil to nitrogen gas and nitrogen oxide gases by dentrifying bacteria in soil, reduces soil fertility, occurs in anaerobic conditions

Root absorption - plants absorb nitrogen as soluble ions, mainly as nitrates but also ammonium ions

Nitrification - oxidation of ammonium ions to nitrites then to nitrates by nitrifying bacteria in soil

Ammonification -

Leaching - high solubility of nitrates means they're easily leached out of soils into water bodies where they act as nutrients for aquatic plants and algae

Food chains - nitrogen passes between organisms as amino acids and proteins in food

Fixation - some micro-organisms can chemically reduce nitrogen to ammonia, can be bacteria in soil or in root nodules of legumes

Human impacts

Agriculture:

  • use of nitrate fertilisers may increase leaching problems including eutrophication, espc if there's heavy rain or its close to a river
  • drainage of fields makes soil more aerobic which increases nitrifying bacteria and decreases dentrifying bacteria
  • ploughing disturbs soil which increases rate of decomposition of DOM releasing more nitrogen oxides into atmosphere
  • leguminous plants e.g peas, beans and clover are grown to increase nitrogen levels in soil which crops then absorb

Pollution:

  • oxides of nitrogen released into atmosphere by combustion so subsequently increase amount washed into soil by rain

Haber process:

  • industrial process to form ammonia from nitrogen and hydrogen
  • uses iron catalyst at high pressure and temperature
  • uses lots of energy
  • ammonia may be converted to nitrates
  • main purpose is manufacture of agricultural fertilisers

Sustainable management:

Management of biological wastes:

  • enzymes produced by bacteria remove amino groups which dissolves ammonium ions, can be useful or cause issues

Organic fertilisers:

  • wastes such as manure, sewage and food production waste used as organic fertilisers to increase nutrient and humus levels
  • may be ploughed into soil , applied to surface, composted aerobically, digested anaerobically or before fertilisers
  • reduce bulk of material making application easier
  • produces fertiliser with better carbon, nitrogen ratio
  • composting and digestion reduce carbon content as CO2 or CH4 gases are lost leaving more nitrogen rich fertiliser

Control of NOx releases:

  • use post-combustion processes e.g catalytic converters and urea sprays

Eutrophication:

  • biological wastes may be washed into water or deliberately put there
  • ammonium compounds converted to nitrites then nitrates, causing eutrophication

Control of combustion process:

  • reduction in use of fossil fuels
  • principles of circular economy
    • more low temp manufacturing processes e.g polymers produced by living organisms rather than using fossil fuels

Management of soil processes:

  • farming practises can be changed to increase soil nitrate levels
    • cultivation of legume crops
    • crop rotation
    • minimal use of pesticides that harm soil biota
    • control of nitrate leaching
    • not applying fertilisers during rain or when it's likely
    • use of low solubility fertilisers e.g urea
    • use of low tillage techniques to reduce soil disturbance
    • uncultivated 'buffer strips' left along rivers
    • minimal use of nitrate fertiliser where leaching into aquifers is likely