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Rhea Mohan Honors Chemistry 1st Semester Review 1st Period…
Rhea Mohan Honors
Chemistry
1st Semester
Review
1st Period
Periodic Table
Periodic Trends
Electronegativity
tendency of an atom to attract a shared pair of electrons towards itself
increase left to right, decrease up to down
Ionic Radius
radius of an atom's ion in ionic crystals structure
decrease left to right, increase up to down
Atomic Radius
measure of the size of its atoms, usually the mean or typical distance from the center of the nucleus to the boundary of the surrounding cloud of electrons
decreases left to right, increases up to down
Periodic Table Groups
Noble gasses
gaseous elements helium, neon, argon, krypton, xenon, and radon, occupying Group 0 (18)
Alkali Metals
found in group 1 of the periodic table (formerly known as group IA), are very reactive metals that do not occur freely in nature
Hallogen group
five non-metallic elements found in group 17 (salt formers)
Alkaline Earth Metals
six chemical elements in group 2
Transition Metals
Metaloids
Metalloids are the elements found along the stair-step line that distinguishes metals from non-metals
Vocab
electromagnetic spectrum
classified by wavelength into radio wave, microwave, terahertz (or sub-millimeter) radiation, infrared, the visible region that is perceived as light, ultraviolet, X-rays and gamma rays
colors identify the element through radioactive decay and release of gamma rays
ionization energy
qualitatively defined as the amount of energy required to remove the most loosely bound electron, the valence electron, of an isolated gaseous atom to form a cation
Atomic Structure
Atomic Models
E. Rutherford (atomic nucleus)
electrons orbiting a fixed, positively charged nucleus in set, predictable paths
N. Bohr (planetary model)
atom as a small, positively charged nucleus surrounded by electrons that travel in circular orbits around the nucleus
J.J. Thompson (plumb pudding)
electrons surrounded by soup of positive charge
Democritus
round sphere with no electrons, protons, or neutrons
first atomic model
J. Dalton
atoms indivisible particles similar to plum pudding
Classifications of Matter
MATTER
PURE
- cannot be separated physically
ELEMENT - only one type of atom
Oxygen
Carbon
COMPOUND - two or more types of atoms
Salt (NaCl)
Water (H2O)
MIXTURE
- can be physically separated
HOMOGENEOUS - solution, uniform throughout
salt disolved in water
HETEROGENEOUS - nonuniform
chocolate chip cookie, soil
Subatomic Particles
neutron
Most mass of all subatomic particles
no charge
determines isotopes
in neucleus
electron
least amount of mass (practically none)
negative charge -1
determine many physical phenomena
in electron shells outside of nucleus
proton
positive charge +1
slightly less mass than neutron
in neucleus
Vocab
atomic mass
mass of an atom of a chemical element expressed in atomic mass units
atomic number
number of protons in the nucleus of an atom, which determines the chemical properties of an element and its place in the periodic table
mass number
number of protons and neutrons in the atom
isotope
two or more forms of the same element that contain equal numbers of protons but different numbers of neutrons in their nuclei, and hence differ in relative atomic mass but not in chemical properties
half life
the time taken for the radioactivity of a specified isotope to fall to half its original value
equations
Physical and Chemical Properties/Changes
Physical vs Chemical Properties
Physical Properties:
color
Molecular Weight
volume
state
5 senses
Chemical Properties:
reactivity
flammibility
oxidation states
heat of combustion
toxicity
Physical vs Chemical Changes
Physical Changes:
separate mixture into compounds
change of state
crystalize
change of strength/duribility
change in texture
Chemical Changes:
decomposition
combustion
change of chemical makeup
Radioactivity/Radiation
Types of Radiation:
Beta
high energy/speed positron
radioactive decay of nucleus releases beta particles
one more proton one less neutron
Gamma
most destructive
photons with highest range
Alpha
identical to helium 4, 2 protons 2 neutrons
least dangerous
Radioactive Decay:
Alpha Decay
Beta Decay
Gamma decay
Nuclear Fission vs Fussion
nuclear fussion
two light nuclei combine into one
releases vast amounts of energy
nuclear fission
splitting heavy unstable nucleus into 2 lighter nuclei
releases heat energy
bombarded with neutrons
Electron Configuration/Quantum Numbers
Quantum Numbers
l
orbital angular momentum quantum number - block 0 1 2 3
m(l)
the magnetic quantum number - -n to +n
n
principle quantum number - energy level 1 2 3 4
m(s)
electron spin quantum number - m(l) +or- 1/2
Electron Configuration Rules
Pauli Exclusion Principle
quantum mechanical principle which states that two or more identical fermions (particles with half-integer spin) cannot occupy the same quantum state within a quantum system simultaneously
Heisenberg Uncertainty Principle
you can never simultaneously know the exact position and the exact speed of an object
Aufbau Principle
ground state of an atom or ion, electrons fill atomic orbitals of the lowest available energy levels before occupying higher levels
Hunds rule
every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, and all electrons in singly occupied orbitals have the same spin
Vocab
Compounds/Reactions
Ionic vs Covalent Compounds
Properties
Properties of Ionic Compounds
Conductive when liquid - Ions are charged particles, but ionic compounds can only conduct electricity if their ions are free to move. Ionic compounds do not conduct electricity when they are solid - only when dissolved in water or melted.
High melting and boiling points - Ionic bonds are very strong - a lot of energy is needed to break them. So ionic compounds have high melting and boiling points.
Properties of covalent Compounds
covalent compounds softer then ionic compounds
Covalent compounds don’t conduct electricity
Covalent compounds don’t dissolve well in water
Covalent compounds are more likely to be flammable
Lewis Structures
resonance
mesomerism is a way of describing delocalized electrons within certain molecules or polyatomic ions where the bonding cannot be expressed by one single Lewis structure
Ionic
chemical bond that involves the electrostatic attraction between oppositely charged ions, and is the primary interaction occurring in ionic compounds
Covalent
Electrons exist outside of an atom ‘s nucleus and are found in principal energy levels that contain only up to a specific number of electrons.
Lewis symbols are diagrams that show the number of valence electrons of a particular element with dots that represent lone pairs.
Types of Chemical Reactions
Decomposition
chemical reaction in which a single compound breaks down into two or more elements or new compounds
Single Replacement
chemical reaction where an element reacts with a compound and takes the place of another element in that compound
Combustions
exothermic reaction in which something reacts with oxygen. The combustion of organic compounds usually takes the form organic compound + oxygen => water + carbon dioxide
Double Replacement
type of chemical reaction where two compounds react, and the positive ions (cation) and the negative ions (anion) of the two reactants switch places, forming two new compounds or products.
Synthesis
synthesis reaction is a type of reaction in which multiple reactants combine to form a single product. Synthesis reactions release energy in the form of heat and light, so they are exothermic
Equilibrium
Equilibrium Equation
k > 1 product favored
K < 1 reactant favored
k = 1 neither favored
Le Chatelier's principle
when a system at equilibrium is placed under stress, the system wi9ll change to relieve stress and reach equilibrium again
Vocab
law of mass action
k = cC dD / aA bB
Equilibrium Constant
Keq = Products/reactants
Acids/Bases
Ph and pOH
antilog
pH sclae
Examples
Properties
Solutions
Characteristics of solutions
Factors effecting Solubility
Concentration
Vocabulary
Solubility
Stoichiometry
Mole/mole ratios
limiting/excess reagents
have - used = remaining
mol limit x mol excess/mol limiting RATIO = mol # excess
converting Mass/moles
theoretical yeild
amount reacted measured by limiting reagent
Converting Moles/mass
% yeild
(actual yield / theoretical yield) x 100 = % yield
Kinetics
Collision theory
Endo/exo Rx diagrams
Rx Rates
([ A ] t2 - [ A ] t1) / t2 - t1
Factors of Rx Rates
Method of initial rates
Thermochem
Specific heat
heat required to change 1g substance by i degree celcius
Law of Conservation of Energy
q = mcAt
heat lost/gained = mass x specific heat x change in temp
Calorimetry
amount of heat lost or gained measured by calorimeter
Types of energy
1 joule = 1 kg m^2 / s^2
1 calorie = 4.184 J
Direction of heat flow
heat of fusion
333 J/g
melting + freezing -
heat of vaporization
2240 J/g
condense + evaporate -
States of Matter
pressure
concepts of kinetic molar theory
These particles are much smaller than the distance between particles. Most of the volume of a gas is therefore empty space.
There is no force of attraction between gas particles or between the particles and the walls of the container.
These particles move in a straight line until they collide with another particle or the walls of the container
Collisions between gas particles or collisions with the walls of the container are perfectly elastic. None of the energy of a gas particle is lost when it collides with another particle or with the walls of the container.
Gases are composed of a large number of particles that behave like hard, spherical objects in a state of constant, random motion
The average kinetic energy of a collection of gas particles depends on the temperature of the gas and nothing else.
Phase Changes
Phase diagrams
Behavior of gases
low density, 1/1000 of liquid or solid equivalent
compressable
fluid (ability to flow)
effuse and diffuse (passive movement)
expand to fill containers
Gases
Ideal Gas Constant
r= 0.0821 ATM
Avogadro's principle
gas at constant temp and pressure, volume proportional to # of mol of gas
Gas Laws
Boyle's law - inverse proportion pressure and temp
P1V1=P2V2
Charles' law - volume of gas proportional to temp
V1/T1 = V2/T2
Gay Lussac's law - pressure and temp related IF VOLUME IS CONSTANT
P1/T1 V = P2/T2 V
Combined gas law
P1V1/T1 = P2V2/T2
PV=nRT
pressure x volume = number of moles x (gas constant) x Temperature IN KELVIN
KMT
Gases are composed of a large number of particles that behave like hard, spherical objects in a state of constant, random motion.
These particles move in a straight line until they collide with another particle or the walls of the container.
These particles are much smaller than the distance between particles. Most of the volume of a gas is therefore empty space.
There is no force of attraction between gas particles or between the particles and the walls of the container.
Collisions between gas particles or collisions with the walls of the container are perfectly elastic. None of the energy of a gas particle is lost when it collides with another particle or with the walls of the container.
The average kinetic energy of a collection of gas particles depends on the temperature of the gas and nothing else.
Dalton's law of partial pressures
P= p1+p2+p3...