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Metals in Biology (Case 3: Superoxide Dismutase (CuZnSOD (Copper Redox…
Metals in Biology
Case 3: Superoxide Dismutase
free radicals
Superoxide radical
Superoxide dismutase
Kinetics
CuZnSOD
Copper Redox chemistry
Inner Sphere vs Outer sphere electron transfer
Overall redox chemistry
Zinc
Active site
Mechanism
Motor Neuron Disease
Case 1: Valinomycin
Transport catalyst
Ligand Binding
Bidentate Ligands
The chelate effect
in medicine and biology
Entropy
The macrocyclic effect
Alkali-Metal Ions in Aqueous Solution
Conformational change
Valinomycin
Case 4: Hydrogenase
Ancient Enzymes
Considerations
Iron Sulpfur World Theory
Ferredoxins
The active site-H-cluster-CO and CN-
mechanism?
Why CO and CN-
Case 2: Carbonic Anhydrase (CA)
CO2 regulation
carbonic anhydrase
Zinc
Mechanism of Action of hCAII
Cadmium
General Concepts
Ionisation Energy
Nuclear charge
Effective nuclear charge
Shielding
Oxidation states
in molecules
fixed oxidation states
variable oxidation states
Transition metals
Effects of Oxidation state Change
Lewis Acids and Bases
Examples
Definitions
Simultaneous Lewis Base and Acid
Acid Base pairs
stability constants
Hard-Soft Acid-Base
Definition
Classification
Catalysis