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CHARACTERISATION OF DIFF. SATES OF MATTER (characterisation of liquids,…
CHARACTERISATION OF DIFF. SATES OF MATTER
characterisation of liquids
viscosity
definition
resistance liquid to flow
flow by sliding molecules over each other
higher, stronger IMF
surface tension
definition
disebabkan net inward force experienced by molecules at surfcae
(toward interior of liq)
molecules dkt surface only attract to sebelah and bawah dia
water: 7.29 x 10^-2 J/m^2
mercury:4.6 x 10^-1 J/m^2 (stronger sbb metallic bond)
dielectric constant
definition
ability to store electric charge
to design separation/ chromatography
boiling point
definition
temp. when vapor of liquid = current atm pressure
if atm pressure=1atm, ---->normal B.P
higher, higher pressure
vapor pressure
definition
pressure of molecules exert on surface of liq.
if x equilibrium, liq. evaporate
higher, lower B.P
factors determining
temp. liquid increase, V.P increase
higher kinetic e, more evaporate
IMF increase, V.P decrease
why? less likely to vaporate
characterisation of solid
techniques utk tnegok
DSC (differential scanning calorimetryanisotropic
thermoanalytical technique
difference amt heat needed to raise temp. of sample & reference measured as function of temp.
reference & sample maintain at same temp.
tengok nota utk graph
x-ray diffraction
get structural info of crystalline
utk tau 3D structure
how?
crystalline atom ada regular pattern
produce regular diffraction pattern
give info abt crystal struc,
amorphous
-random arrangement
scattered beams :
form constructive interference in some directions
produce diffracted beams
no distinctive pattern
lambda=2dsin'tita'
infrared spectroscopy
lambda infrared> lambda light
f infrared< f visible light
principle: movement of molecule = feq. of infrared
differentiate intermolecular bond between diff. polymorph
peak shift due to hydrogen bond
optical microscope
amorphous solid
physical properties same bila measured in any direction
isotropic subs.
refractive index
identical
along each crystal axes
ada single refraction
crystals
mechanical, electrical, magnetic, optical properties beza ikut direction measured
anisotropic
detected by refractive index using polarizing lens
diff. refractive index result in double refraction/ birefringence
cubic crystal EXCEPTION
highly symmetrical internal arrangement
isotropic
refractive index identical along each crystal axes
ada single refraction
scanning electron microscope
for surface analysis (morphology)
record
TEM (transmitted through object)
lighter region
SEM (electrons reflected by object)
darker region
quantitative info utk characterization of particles
u-endo, melting point
n-exo
----no exothermic