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Sriya Popuri Period A (Periodic Trends (Electron Affinity (Increases right…

- - - - Heat
      - Entropy
- - - - Energy cannot be created or destroyed
      - Entropy of universe always increases
      - Entropy of a crystal at 0 K is 0
    - - ΔG is related to equilibrium constant (see Formula)
- - - - Rate=k[A]ᵐ[B]ⁿ
        
        M and N Found Experimentally
        
        M and N Found through rate determining step constants
        
        Rate Determining Step is the slowest reaction mechanism
        
        Reaction Mechanism consists of elementary steps
        
        Unimolecular
        
        Bimolecular
        
        Termolecular (3 particles)
      - Covers Initial Rate
    - - Covers constant rate
        
        First Order- ln[A]
        
        Second Order- 1/[A]
        
        Zeroeth Order- [A]
      - Used to find half life
        
        First Order= ln(2)/k
        
        Zeroeth Order= [A]/2k
        
        Second Order 1/k[A]
      - Slope is -k unless second order, where it is k.
  - - - A is frequency factor
      - Ea is activation energy
      - T is in Kelvin, R is 8.134 J(mol*K)
- - - - Kc = Kp(RT)^dn