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Chemistry Topic 1 (Topic 1 Atomic Structure (Atomic Structure (Subatomic…
Chemistry Topic 1
Topic 1 Atomic Structure
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Atomic Structure
In 1897, an English physicist called J. J. Thomson discovered electrons. He modelled the atom as a 'plum pudding' - a ball of positive charge (like dough), with negative electrons (currants) mixed in.
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In 1932, James Chadwick discovered that some particles in the nucleus have no charge at all. He called them neutrons. Electrons (negatively charged particles) have been shown to orbit the nucleus at fixed distances.
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Bohr discovered that electrons orbit the nucleus at fixed distances. Chadwick discovered that some particles in the nucleus, called neutrons, have no charge at all.
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Subatomic
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An atom consists of electrons orbiting a central nucleus. The radius of the nucleus is about 10,000 times smaller than the radius of the atom, but almost all the atom's mass is concentrated in the nucleus.
An atom consists of electrons orbiting a central nucleus. The radius of the nucleus is about 10,000 times smaller than the radius of the atom, but almost all the atom's mass is concentrated in the nucleus.
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Isotopes
Isotopes for Hydrogen
Deuterium
Deuterium is a hydrogen atom with 1 proton and 1 neutron. Around 0.02% of hydrogen atoms are deuterium.
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Relative Atomic Mass
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Calculating
The relative atomic mass (Ar) is the average mass of all of the isotopes of an element. It takes into account how often each isotope is found (the isotope abundance).
The relative atomic mass (Ar) is the average mass of all of the isotopes of an element. It takes into account how often each isotope is found (the isotope abundance).
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Definition
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Filling Electron Shells
Electrons fill an atom's shells in order of increasing energy. The closer a shell is to the nucleus, the lower its energy, so the first shell that is filled is the closest to the nucleus.
Electron Configuration
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The inner shell (closest to the nucleus) can have a maximum of 2 electrons and the next two shells can have a maximum of 8 electrons.
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Periodic Table
History
Newland
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However, the table was incomplete, and some elements were placed in inappropriate groups.
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Current Table
The discovery of protons and isotopes has shown that Mendeleev ordered elements exactly by atomic number (number of protons).
Therefore, the modern periodic table looks very similar to Mendeleev's (except the gaps are filled).
Order
The metals are found on the left side of the periodic table because they have few electrons in their outer electron shell.
Periods
The table is ‘periodic’ because elements with similar properties occur at regular intervals, i.e. periodically.
Therefore, the rows of the periodic table are called periods.
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Groups
Elements in the same column have the same number of electrons in their outer shell (the highest energy level).
Columns are called groups, and the group number equals the number of electrons an atom of that element has in its outer shell.
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Predicting Trends
Because all elements in a column have the same number of electrons in their outer shell, they have similar chemical properties.
This means they will all react in similar ways.
Types
Metals
Where they are found
Metals are found on the left of the periodic table because they have few electrons in their outer shell.
When metals react, they lose 1 or more of these negatively charged electrons to form positively charged ions.
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Non Metals
Where they are found
Non-metals are found on the right of the periodic table because they have many electrons in their outer shell.
When non-metals react, they either:
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Noble Gasses
Properties
Inert
The elements in group 0 are unreactive because they have a full outer shell of electrons. They do not gain or lose electrons to fill up this shell as it is already full.
They can be used in light bulbs because the noble gases will not react with the hot metal filament.
Monotonic
Because noble gases are unreactive, they exist as single atoms (monatomic) instead of forming molecules.
Low Boiling Point
The noble gases have low boiling points.
But their boiling points do increase as you move down the periodic table. This is because the relative atomic mass increases lower down the periodic table.
Low Density
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Their densities do increase as you move down the periodic table because of their increasing relative atomic mass.
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Halogens
Elements in group 7 in the periodic table are called halogens. They have 7 electrons in their outer shell. They are very reactive because they easily accept an electron into this outer shell. They have similar properties and react in similar ways.
Structure
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When they react, they gain 1 electron to get a full outer shell.
By gaining 1 electron, they form a negative ion.
In their elemental form, halogens share electrons to make diatomic molecules (molecules made of pairs of atoms).
When a metal atom transfers its outer electron to a non-metal atom (like a group 7 atom), salts are formed.
The result is a compound where all the ions have a full outer shell.
Trend
As you go down the group, the halogens become less reactive. This is because:
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Alkali Metals
Where they are found
The elements in group 1, found on the far left of the periodic table, are called the alkali metals.
Trends
The number of electron shells increases meaning there is a greater distance between the outer electron and the nucleus.
As you move down group 1 of the periodic table, the reactions of alkali metals become quicker and more vigorous. This is because:
The greater the distance between the outer electron and the nucleus, the weaker the attraction between them.
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